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Volume 1, June 2014, Pages 18-39
Lubricity of bio-based lubricant derived from chemically modified jatropha methyl ester
N.W.M. Zulkiflia, H.H. Masjukia, M.A. Kalama, R. Yunusb, S.S.N. Azmana
a Department of Mechanical Engineering, University of Malaya, Kuala Lumpur 50603, Malaysia
b Institute of Advanced Technology, Universiti Putra Malaysia, 43400 Serdang, Selangor, Malaysia
Abstract
Many studies have been undertaken with a view to using chemically modified vegetable oil as a bio-based lubricant. This research focused on tribological properties of trimethylolpropane (TMP) ester, which is derived from renewable resource. This TMP ester was produced from jatropha methyl ester; it is biodegradable and has high lubricity properties. Two different conditions of lubrication are being investigated: extreme pressure and anti-wear. It was found that the TMP ester (Jatropha) has better lubricity in terms of wear and friction compared to paraffin oil under extreme pressure conditions. TMP ester (Jatropha) has similar characteristics to fully formulated lubricant (FFL), in terms of the coefficient of friction (CoF). In terms of the anti-wear condition, TMP ester (Jatropha) has the lowest CoF; however it also has the high wear scar diameter. This is due to corrosion and chemical attack.
Keywords
Synthetic lubricant; Bio-based lubricant; Jatropha
Full Text
References
AL-Bukhaiti,
M. A., Al-Hatab, K. A, & Gabbert, Ulrich, 2011. The Influence af
High Contact Stresses and Lubricant Type an the Rolling Contact
Fatigue Life and Failure Mode of Aisi 52100 Steel Balls. Emirates
Journal for Engineering Research, 16(1), 9-22.
Arbain,
Noor Hafizah, & Salimon, Jumat, 2011. Synthesis and characterization
of ester trimethylolpropane based Jatropha curcas oil as
biolubricant base stocks. Journal of Science and Technology, 2(2).
Bockish,
M., 1998. Fats and Oils Handbook,Champaign, IL,838
Bokade,
V. V., & Yadav, G. D., 2007. Synthesis of Bio-Diesel and
Bio-Lubricant by Transesterification of Vegetable Oil with Lower and
Higher Alcohols Over
Heteropolyacids Supported by Clay (K-10). Process Safety and
Environmental Protection, 85(5), 372-377.
Erhan, S. Z., &
Asadauskas, S., 2000. Lubricant basestocks from vegetable oils.
Industrial Crops and Products, 11(2), 277-282.
Erhan, S. Z.,
Sharma, B. K., & Perez, J. M., 2006. Oxidation and low temperature
stability of vegetable oil-based lubricants. Industrial Crops and
Products, 24(3), 292-299.
Erhan, Sevim Z.,
Sharma, Brajendra K., Liu, Zengshe, & Adhvaryu, Atanu, 2008.
Lubricant Base Stock Potential of Chemically Modified Vegetable
Oils. Journal of Agricultural and Food Chemistry, 56(19), 8919-8925.
Fernández Rico, J.
E., Hernández Battez, A., & Garcı́a Cuervo, D., 2002. Wear
prevention characteristics of binary oil mixtures. Wear, 253(7–8),
827-831.
Fox, N.J., &
Stachowiak, G.W., (2007). Vegetable oil-based lubricants—a review of
oxidation. Tribology International 40(7), 1035-1046.
Goodrum, J.W., &
Geller, D.P., 2005. Influence of fatty acid methyl esters from
hydroxylated vegetable oils on diesel fuel lubricity. Bioresource
Technology 96(7), 851-855.
Gryglewicz, S.,
Muszyński, M., & Nowicki, J., 2013. Enzymatic synthesis of rapeseed
oil-based lubricants. Industrial Crops and Products 45, 25-29.
Gryglewicz, S.,
Piechocki, W., & Gryglewicz, G., 2003. Preparation of polyol esters
based on vegetable and animal fats. Bioresource Technology, 87(1),
35-39.
Hamblin, P.,
(1999). Oxidative stabilisation of synthetic fluids and vegetable
oils. Journal of Synthetic Lubrication, 16(2), 157-181.
Hamid, H. A., Yunus,
R., Rashid, U., Choong, T. S. Y., & Al-Muhtaseb, A. H., 2012.
Synthesis of palm oil-based trimethylolpropane ester as potential
biolubricant: Chemical kinetics modeling. Chemical Engineering
Journal, 200–202(0), 532-540.
Hamrock, Bernard J,
& Dowson, Duncan, 1981. Ball bearing lubrication: the
elastohydrodynamics of elliptical contacts.
Havet, L., Blouet,
J., Robbe Valloire, F., Brasseur, E., & Slomka, D., 2001.
Tribological characteristics of some environmentally friendly
lubricants. Wear, 248(1-2), 140-146.
He, Z. Y., Song, Y.
P., Shao, H. Y., Zhan, W. Q., & Ren, T. H., 2005. A study of the
synergistic effect of a triazine-dithiocarbamate derivative with tcp
in vegetable oil. Journal of Synthetic Lubrication, 21(4), 287-297.
He, Zhongyi, Lu,
Jinliang, Zeng, Xiangqiong, Shao, Heyang, Ren, Tianhui, & Liu,
Weimin, 2004. Study of the tribological behaviors of S, P-containing
triazine derivatives as additives in rapeseed oil. Wear, 257(3–4),
389-394.
Husnawan, M., Saifullah, M. G., & Masjuki, H. H., 2007. Development
of friction force model for mineral oil basestock containing palm
olein and antiwear additive. Tribology International, 40(1), 74-81.
Hwang, Hong-Sik, &
Erhan, Sevim, 2001. Modification of epoxidized soybean oil for
lubricant formulations with improved oxidative stability and low
pour point. Journal of the American Oil Chemists' Society, 78(12),
1179-1184.
Hwang, Hong-Sik, &
Erhan, Sevim Z., 2006. Synthetic lubricant basestocks from
epoxidized soybean oil and Guerbet alcohols. Industrial Crops and
Products, 23(3), 311-317.
Ing, Tiong Chiong,
Mohammed Rafiq, A. K., Azli, Y., & Syahrullail, S., 2012. The Effect
of Temperature on the Tribological Behavior of RBD Palm Stearin.
Tribology Transactions, 55(5), 539-548.
Kodali, D. R.,
2002. High performance ester lubricants from natural oils.
Industrial Lubrication and Tribology, 54(4), 165-170.
Lathi, Piyush S., &
Mattiasson, Bo, 2007. Green approach for the preparation of
biodegradable lubricant base stock from epoxidized vegetable oil.
Applied Catalysis B: Environmental, 69(3–4), 207-212.
Lawal, Sunday
Albert, Choudhury, Imtiaz Ahmed, & Nukman, Yusoff, 2013. A critical
assessment of lubrication techniques in machining processes: a case
for minimum quantity lubrication using vegetable oil-based
lubricant. Journal of Cleaner Production, 41(0), 210-221.
Lugt, P. M., Severt,
R. W. M., Fogelströ, J, & Tripp, J. H., 2001. Influence of surface
topography on friction, film breakdown and running-in in the mixed
lubrication regime. Proceedings of the Institution of Mechanical
Engineers, Part J: Journal of Engineering Tribology, 215(6),
519-533.
Maleque, M. A.,
Masjuki, H. H., & Haseeb, A. S. M. A., 2000. Effect of mechanical
factors on tribological properties of palm oil methyl ester blended
lubricant. Wear, 239(1), 117-125.
Maleque, MA,
Masjuki, HH, & Sapuan, SM, 2003. Vegetable-based biodegradable
lubricating oil additives. Industrial Lubrication and Tribology,
55(3), 137-143.
Masjuki, H. H.,
Maleque, M. A., Kubo, A., & Nonaka, T., 1999. Palm oil and mineral
oil based lubricants—their tribological and emission performance.
Tribology International, 32(6), 305-314.
Nogueira, I., Dias,
A. M., Gras, R., & Progri, R., 2002. An experimental model for mixed
friction during running-in. Wear, 253(5–6), 541-549.
Padgurskas, Juozas,
Rukuiza, Raimundas, Prosyčevas, Igoris, & Kreivaitis, Raimondas,
2013. Tribological properties of lubricant additives of Fe, Cu and
Co nanoparticles. Tribology International, 60(0), 224-232.
Pramanik, K., 2003.
Properties and use of jatropha curcas oil and diesel fuel blends in
compression ignition engine. Renewable Energy, 28(2), 239-248.
Sarhan, Ahmed AD,
Sayuti, M, & Hamdi, M., 2012. Reduction of power and lubricant oil
consumption in milling process using a new SiO 2 nanolubrication
system. The International Journal of Advanced Manufacturing
Technology, 1-8.
Schuchardt, Ulf,
Sercheli, Ricardo, & Vargas, Rogério Matheus, 1998.
Transesterification of vegetable oils: a review. Journal of the
Brazilian Chemical Society, 9, 199-210.
Singh, T.,
Bhattacharya, A., & Verma, V. K., 1992. A study in EP activity
evaluation of some new oil-soluble Mo-S complexes. Tribology
International, 25(6), 381-385.
Uosukainen, Esa,
Linko, Yu-Yen, Lämsä, Merja, Tervakangas, Tommi, & Linko, Pekka,
1998. Transesterification of trimethylolpropane and rapeseed oil
methyl ester to environmentally acceptable lubricants. Journal of
the American Oil Chemists' Society, 75(11), 1557-1563.
Freedonia Group,
2013.World Lubricants to 2017, Preston Road, Dallas.
Yunus, Robiah, Fakhru'l-Razi, Ahmadun, Ooi, Tian Lye, Iyuke, Sunny
E., & Perez, Joseph M., 2004. Lubrication properties of
trimethylolpropane esters based on palm oil and palm kernel oils.
European Journal of Lipid Science and Technology, 106(1), 52-60.